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The Spring container processes the <aop:aspectj-autoproxy> element and automatically creates a dynamic proxy required for AOP when it wires the beans together. Proxies are automatically added to the CaculateSpringAOP class by Spring, allowing for interception and the application of the LoggingAspect. Note that you must add the highlighted AOP schema and namespace before the <aop:aspectjautoproxy> element can work. In this case, Spring 2 uses the AspectJ pointcut language (described in the next section) to determine where the proxies should be added for interception by the aspect.

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There is ample evidence that s bonds do interact with other occupied orbitals and that s orbitals interact with other empty orbitals Evidence for the latter case is primarily in the form of chemical activation of C H bonds by adjacent groups with low-lying empty or half- lled orbitals The increased acidity of C H bonds, that is, reactivity with Lewis bases, under these circumstances is discussed in 10 Several examples will serve to exemplify the interaction of s bonds with adjacent lled orbitals In the following discussion, the s bond will be represented by the sp 3 hybrid orbital of the C atom The important point to note is that this orbital is 75% p character and interacts with immediately adjacent neighbouring groups, including other s bonds, in a p fashion.

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Interaction of s bonds with neighboring s bonds depends on the orientation of one bond relative to the other (Figure 46) It is clear that the interaction is minimized (but not zero) when the two bonds are perpendicular to each other (Figure 46a) since then the adjacent sp n hybrid orbitals lie approximately in each other's nodal planes It is not immediately obvious, however, whether the coplanar anti (Figure 46b) or the coplanar syn (Figure 46c) arrangement results in maximum interaction In fact, a large body of experimental data has been interpreted to show that the coplanar anti arrangement represents the strongest interaction between adjacent s bonds [6, 84] Rates of electron transfer through chains of saturated C C bonds con rm the anti con guration is the most e ective for promoting through-bond coupling [85].

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The interactions are repulsive in the four-electron case (s s), attractive in the two-electron case (s s ), as expected It has been demonstrated that the attractive s s interactions are more important than the repulsive s s interactions and are responsible for the rotational barrier in ethane and ethanelike molecules, H3 X YH3 (X,Y C, Si, Ge, Sn, Pb) [86] As well as the relative orientation of the bonds, the extent of interaction will depend on the polarizations of the bonds Bonds from C to an element less electronegative than C will have the larger coe cient on C in the s orbital and smaller in the s orbital Therefore, the two s bonds will experience a stronger interaction than the two s orbitals This situation is depicted in Figure 47a This is the case if the substituent is a metal..

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